Bắt đầu: 24/09/2023 21:15
Sân: Jorge Figueroa Vázquez
Lịch sử đối đầu Rayo Vallecano vs Villarreal |
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| 29.05.2023 | Rayo Vallecano | 2-1 | Villarreal |  | |
| 31.01.2023 | Villarreal | 0-1 | Rayo Vallecano | | |
Phong độ của Rayo Vallecano |
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| 16.09.2023 | Rayo Vallecano | 2-0 | Alaves | | ||
| 08.09.2023 | AD Alcorcon | 2-2 | Rayo Vallecano | | ||
| 03.09.2023 | Real Betis | 1-0 | Rayo Vallecano | | ||
| 29.08.2023 | Rayo Vallecano | 0-7 | Atletico Madrid | | ||
| 22.08.2023 | Granada CF | 0-2 | Rayo Vallecano | | ||
| 12.08.2023 | Almeria | 0-2 | Rayo Vallecano | | ||
| 06.08.2023 | Brighton Hove Albion | 1-1 | Rayo Vallecano | | ||
| 03.08.2023 | Real Valladolid | 3-2 | Rayo Vallecano | | ||
| 30.07.2023 | FC Porto | 1-1 | Rayo Vallecano | | ||
| 23.07.2023 | Charleroi | 1-1 | Rayo Vallecano | | ||
Phong độ của Villarreal |
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| 21.09.2023 | Panathinaikos(N) | 2-0 | Villarreal | | ||
| 17.09.2023 | Villarreal | 2-1 | Almeria | | ||
| 02.09.2023 | Cadiz | 3-1 | Villarreal | | ||
| 27.08.2023 | Villarreal | 3-4 | FC Barcelona | | ||
| 19.08.2023 | Mallorca | 0-1 | Villarreal | | ||
| 14.08.2023 | Villarreal | 1-2 | Real Betis | | ||
| 06.08.2023 | Newcastle United | 4-0 | Villarreal | | ||
| 05.08.2023 | Nice(N) | 1-1 | Villarreal | | ||
| 31.07.2023 | Sporting CP | 3-0 | Villarreal | | ||
| 28.07.2023 | Feyenoord | 1-1 | Villarreal | | ||